GUTMANN BRAGA PDF
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The catalysts show similar catalytic efficiency as the homogeneous catalyst in the model cyclopropanation between ethyl diazoacetate EDA and bfaga. Heterogeneous self-supported dirhodium II catalysts with high catalytic efficiency in cyclopropanation — a structural study J.
For reproduction of material from PPS: If you are not the author of this article and you wish to reproduce material from it in a third party non-RSC publication you must formally request permission using Copyright Clearance Center. Catalytically active dirhodium sheet-like coordination polymers are brags from their precursors via ligand exchange.
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Residual trifluoroacetate species are investigated by quantitative 19 F MAS NMR which further reflects the configuration of trifluoroacetate in the obtained Rh 2 -bdc Tfand defects in the structure. For reproduction of material from all other RSC journals and books: For reproduction of material from NJC: Back to tab navigation Download options Please wait If you are the author of this article you still need to obtain permission to reproduce the whole article in a third party publication with the exception of reproduction of the whole article in a thesis or dissertation.
Previous Article Next Article. Aany Sofia Lilly Thankamony. Jump to site search. Jump to main content. Reproduced material should be attributed as follows: DR-UV-vis and XPS demonstrate that the oxidation state and the Rh—Rh single bond in the dirhodium node are maintained during the ligand substitution process.
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The stability and reusability of the catalysts are verified by TG-DTA measurements and leaching tests. Authors contributing to RSC publications journal articles, books or book chapters do not need to formally request permission to reproduce material contained in this article provided that the correct acknowledgement is given with the reproduced material. This may take some gutmznn to load.
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The individual lamellae of the dirhodium-bdc frameworks are stacked as parallel sheets, which are randomly oriented or slightly ordered. Back to tab navigation.
XX is the XXth reference in the list of references. The article was received on 26 Apraccepted on 20 Sep and first published on 21 Gutmanm Heterogeneous self-supported dirhodium II catalysts with high catalytic efficiency in cyclopropanation — a structural study.
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